Artificial photosynthesis breakthrough replicates early planting processes
The use of sunlight to convert carbon dioxide and water into sugars and oxygen is a remarkable performance of nature, achieved by the complicated process of photosynthesis. This natural mechanism enables plants to distract energy from sunlight, so that a series of reactions are fueled that support life on earth.
Replication of photosynthesis in a laboratory environment promises considerable benefits. Artificial use of solar energy can enable the conversion of atmospheric carbon dioxide to carbohydrates and other valuable connections. In addition, because the splitting of water is part of photosynthesis, this approach offers the potential for the production of hydrogen fuel by insulating hydrogen and oxygen.
However, recreating this natural process is not a simple task. Photosynthesis includes a series of complex reactions that occur in plant cells, mediated by a network of pigments, proteins and molecules. Despite these challenges, research continues to take steps in simulating the design of nature.
Remarkable progress has been achieved by Professor Frank Wurthner, a chemist at Julius-Maximilians-Universitat (JMU) Wurzburg in Bavaria, Germany. His team successfully replicated one of the first phases of photosynthesis with the help of a series of artificial colorants and performed an in -depth analysis of the behavior of the system.
This research, conducted in collaboration with the Laboratory of Professor Dongho Kim at Yonsei University in Seoul, Korea, was recently published in the Nature Chemistry magazine.
The team developed a coloring assembly that is very similar to plant cell light harvest complexes. The synthetic structure catches light at one end point, facilitates cargo separation and then gradually brings steps through a series of steps to the other end. This assembly has arranged four Pylene bisimide dye molecules in a vertical stack.
“We can specifically activate the cargo transport in this structure with light and have analyzed it in detail. It is efficient and fast. This is an important step in the direction of the development of artificial photosynthesis,” said JMU PHD -Student Leander Ernst, who was responsible for synthetizing the stacked system.
Looking ahead, the JMU researchers are planning to increase the number of dye components in their stack on nano scale to form a supramolecular wire. Such a structure would effectively absorb sunlight and channel energy over larger distances. Achieving this would mean considerable progress in the direction of new photo -functional materials that support artificial photosynthesis.
Research report:Photo-induced step-by-step cargo hopping in p-stacked Pylene Bisimide Donor-Brug acceptor Arrays.